a great way for beginners is to use the circle of 5ths.
The circle of 5ths are all the 12 keys organised in a circle of 5th intervals. The way to use it is to choose a key, then the 5 chords next to it are the basic chords of the key.
For instance in the key of F, the basic chords are: F, Bb, C, Dm, Gm, and Am.
Here's the circle
http://library.thinkquest.org/15413/media/images/circleof5ths.gif Red ones are minor keys, and blue ones are major keys.
Doc-Z